Книга "Phase Transformations" является частью серии книг, которая предлагает студентам более продвинутые инструменты характеризации фаз, изучение всех видов фаз (жидких, газовых и твердых, чистых или многофазных), процессов инженерии, химического и электрохимического равновесия, свойств поверхностей и фаз малых размеров. Макроскопические и микроскопические модели взаимодействуют друг с другом, при этом постоянно поддерживается связь между двумя масштабами. Особое внимание уделяется строгости математических разработок. Пятый том посвящен изучению превращений и равновесий между фазами. Перво- и второго порядка превращения чистых фаз представлены детально, а также макроскопические и микроскопические подходы к равновесию фаз. При представлении бинарных систем подробно обсуждаются термодинамика азеотропии и демиксинга и их применение к строго регулярным растворам. Изучаются эвтектические и перитектические точки, а также соответствующие им реакции. При изучении тройных систем вводятся понятия тройных азеотропов и эвтектик. При рассмотрении каждого типа систем твердое-жидкое учитываются вмешательства определенных соединений с конгруэнтным или не конгруэнтным плавлением. Также демонстрируются особенности различных заметных точек на диаграмме.
The book forms part of a series which provides the advanced student with an introduction to phases, their behaviour and the engineering processes which control them, chemical equilibria and thermodynamic relationships, properties of materials and surface and nano-scale systems and processes. From both the macro- and the micro-scales correlations are developed. Mathematical rigour becomes ever more important; it is fair to state that this is the dominant feature of this volume. It considers phase transitions and phase equilibra between phases. Pure phase transformation to first and of second order are covered in great detail as distinctly from the macro-and microscopics approaches to phase equilibriums. Binary systems in particular have been considered with detailed theoretical and practical development associated with such systems. As an applied example, aseotropic and tailoring solutions have been narrowly examined in unrestricted solution areas, to become tremendous reality in strict solutions. To aid the development and comprehension, Conceptual asepoids and necking diameters have been demonstrated, amongst other beneficial methodologies. The analysis of ternarial systems arose difficulties only to be successfully conquered, introducing the concept of tertiary aseotropes. The eutectic pathway has also been successfully mapped. Systems of solid to liquid interesve with early conceptualized structures have been emphasized. Investigations into action and failures together with individual treatments ASAP composite reactions are probed. However, thermochemical diagrams induct readers to consider impacts of combinations practically from theory to practice. The complex interactions between structures compositions and phase equillibra particularly development of past interact with different bodies of technology have eariened great attention.
This book is part of the series, which aims to offer graduate level students an introductory understanding of various subjects involving the quantitative description of phases in materials; the study of the behaviour of solvents and other substances, their modes of operation and their roles in chemical and biochemical processes; and physical chemistry, including the analysis of surface properties and micro-particle structures. In this volume, all of these issues are combined to cover transformations and equilibrium among phases. Note that the book covers first and second order phase transformation in detail, both macroscopically and microscopically, discussing phase equilibrium. It also goes into considerable depth (much of which is heavily mathematically inclined) on the thermodynamics involved in azoic phase transformations, both ones that cause distinctions in binary solutions, as well reactions involving and excluded eutectic, peritective, ternary, eutectical, and ternity solutions and systems. Considerable emphasis is placed in order to fully elucidate the characteristics of each prominent point in graph theory.
Электронная Книга «Phase Transformations» написана автором Michel Soustelle в году.
Минимальный возраст читателя: 0
Язык: Английский
ISBN: 9781119178583
Описание книги от Michel Soustelle
This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been given to the rigor of mathematical developments. This fifth volume is devoted to the study of transformations and equilibria between phases. First- and second-order pure phase transformations are presented in detail, just as with the macroscopic and microscopic approaches of phase equilibria. In the presentation of binary systems, the thermodynamics of azeotropy and demixing are discussed in detail and applied to strictly-regular solutions. Eutectic and peritectic points are examined, as well as the reactions that go with them. The study of ternary systems then introduces the concepts of ternary azeotropes and eutectics. For each type of solid-liquid system, the interventions of definite compounds with or without congruent melting are taken into account. The particular properties of the different notable points of a diagram are also demonstrated.
