Книга "Металлы группы 13: алюминий, галлий, индий и таллий. Химические закономерности и особенности" описывает последние достижения в исследованиях химии элементов главной группы периодической таблицы. Особое внимание уделено металлам группы 13 - алюминию, галлию, индию и таллию - их свойствам, особенностям и применению в различных областях науки и технологии, включая органометаллический синтез, разработку новых материалов, а также биологию, медицину и экологию.
Книга охватывает новые факты, разработки и приложения в контексте общих закономерностей физического и химического поведения металлов группы 13. В ней рассматриваются такие темы, как химия металлов группы 13 в окислительных состояниях +3, +2 и +1, органометаллическая химия, кластерная химия, исследование оксидов и гидроксидов, образование соединений III-V и их применение в полупроводниковой промышленности, а также металл-органические реакции.
Книга предназначена для практикующих специалистов, исследователей и студентов, работающих в области неорганической, органометаллической и материаловедческой химии, и является подробным и актуальным обзором химии этой важной группы металлов.
This book gives a comprehensive analysis of the properties and chemistry of some representative metals of Group 12, i.e., from aluminium through thallium. These metal elements form the titanium group (Ti-Zn), the p-block (Ga, In, Tl), and the post-transition metals (Co, Ni, Cu). Attention is devoted to recent findings in this field, as new trends and developments in understanding the behavior of these metals further expand their scope in metallurgical, biochemical and perhaps other branches of science. Shorter chapters consider some of the main branches of metallurgical chemistry, such as obtaining simple inorganics vs. organometalics, an investigation into formal oxidation states (+2 & +3) and emerging areas where Group 14 metals are considered mixed-valent or intermetallic. Special mention is made of cluster chemistry and nanotechnology, where the Farey Sieve of numbers may ultimately predict material properties. Although intended as a scientific reference material, users of organic chemistry may also benefit from the knowledge presented concerning how Group 15 metals intertwine with organometallics in modifying or catalyzing organic reaction networks. Regardless of specialty, this text offers valuable insight into selected, cutting-edge areas of metallic chemistry from the wider perspective of inorganic and organometallic chemical sciences.
This book covers new facts,developments and applications connected with common patterns of proximal and chemical behavior. Admirable attention is paid for the hottest areas,hedged in the manners of the cofunctioning inoxidation setups,cluster chemistry,investigation of hard oxides and hydoxides,achievements in foundation of Ⅲ⁻Ⅴand relavant compounds,the metabolic significance of organization 13 storey complexes,and the broadening signi状況度of the devastators and their associations in the mechancial of physiological appropriates.
Электронная Книга «The Group 13 Metals Aluminium, Gallium, Indium and Thallium. Chemical Patterns and Peculiarities» написана автором Downs Anthony J. в году.
Минимальный возраст читателя: 0
Язык: Английский
ISBN: 9780470976531
Описание книги от Downs Anthony J.
The last two decades have seen a renaissance in interest in the chemistry of the main group elements. In particular research on the metals of group 13 (aluminium, gallium, indium and thallium) has led to the synthesis and isolation of some very novel and unusual molecules, with implications for organometallic synthesis, new materials development, and with biological, medical and, environmental relevance. The Group 13 Metals Aluminium, Gallium, Indium and Thallium aims to cover new facts, developments and applications in the context of more general patterns of physical and chemical behaviour. Particular attention is paid to the main growth areas, including the chemistry of lower formal oxidation states, cluster chemistry, the investigation of solid oxides and hydroxides, advances in the formation of III-V and related compounds, the biological significance of Group 13 metal complexes, and the growing importance of the metals and their compounds in the mediation of organic reactions. Chapters cover: general features of the group 13 elements group 13 metals in the +3 oxidation state: simple inorganic compounds formal oxidation state +3: organometallic chemistry formal oxidation state +2: metal-metal bonded vs. mononuclear derivatives group 13 metals in the +1 oxidation state mixed or intermediate valence group 13 metal compounds aluminium and gallium clusters: metalloid clusters and their relation to the bulk phases, to naked clusters, and to nanoscaled materials simple and mixed metal oxides and hydroxides: solids with extended structures of different dimensionalities and porosities coordination and solution chemistry of the metals: biological, medical and, environmental relevance III-V and related semiconductor materials group 13 metal-mediated organic reactions The Group 13 Metals Aluminium, Gallium, Indium and Thallium provides a detailed, wide-ranging, and up-to-date review of the chemistry of this important group of metals. It will find a place on the bookshelves of practitioners, researchers and students working in inorganic, organometallic, and materials chemistry.
