Metal Carbene Complexes is a comprehensive guide that describes the latest advances and strategies for using carbene complexes to synthesize organic molecules. It draws on the experiences and knowledge of many leading researchers in the field to provide a clear, but intuitive, overview of how these potent reagents are employed in a wide range of synthesis projects.
The first section of this work provides a brief introduction to carbene chemistry and introduces the unique properties and different types of metal carbene complexes available for synthetic purposes. Chapter 2 then discusses the most relevant stereoselectivity applications of metal carbenes in several categories such as cyclopropyl, olen, and olefins.
Metal Carbene Complex Chemistry Chapter 3 tells the story of how they could be employed as a catalyst or reagent for metal carbene effects. Chapter 4 describes the applications of carbene for various fine chemicals, including but not limited to pharmaceutical compounds. Finally, Chapter 5 highlights recent advances with carbene formation under neutral conditions.
In addition, this incredible guide includes valuable information about experimental methods, critical reaction mechanisms, and important laboratory concepts developed by leading scientists in the carbene and organic synthesis fields. It also provides detailed insights into recent achievements, thereby creating a vivid compendium about the methods and tools necessary for managing the exciting and challenging world of carbene synthesis.
Эта книга будет полезна как студентам, так и опытным ученым в области химии. Она представляет собой руководство по всем аспектам использования карбеновых комплексов в химическом синтезе. Все новые синтетические методы, которые используют карбеновые комплексы - стереоселективная циклопропонирование, карбонил-олефинирование, метатезис олефинов, и т.д., подчеркиваются в этой книге. Благодаря своим многочисленным сферам применения - от синтеза высокоточных химических веществ до производства полимеров - карбеные комплексы признаны своего рода универсальными соединениями в органическом синтезе, что объясняет их огромное множество и широкий потенциал. Такой текст - краткое изложение всех аспектов использования карбеных комплексов в химических реакциях - послужит катализатором для еще более быстрого развития этой области исследований по мнению Р. Х. Груббса.
Электронная Книга «Metal Carbenes in Organic Synthesis» написана автором Группа авторов в году.
Минимальный возраст читателя: 0
Язык: Английский
ISBN: 9783527614073
Описание книги от Группа авторов
There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes – stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. – reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production. This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes of carbene complexes, their generation, and application in organic synthesis are discussed in detail. Critically selected, up-to-date references and valuable experimental procedures await the reader. Every chemist searching for a concise introduction and reference work for carbene complex chemistry will welcome this practical guide. «…this concise presentation of all the aspects of the use of carbene complexes in synthesis will help provide the impetus for even more rapid developments in this field of research.» R. H. Grubbs (Caltech)
